1-Ethenyl-4-[(phenylsulfanyl)methyl]benzene
نویسندگان
چکیده
منابع مشابه
1-Ethenyl-4-[(phenylsulfanyl)methyl]benzene
The dihedral angle between the aromatic rings in the title compound, C(15)H(14)S, is 72.38 (7)°. In the crystal, the mol-ecules are connected by C-H⋯π inter-actions.
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Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, C(17)H(15)NO(2)S. The mol-ecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e. 82.98 (12) and 84.46 (13)°, respectively. The terminal ethenyl group is almost coplanar with the...
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In the title compound, C(17)H(17)NO(2), the phenyl-ene rings are nearly coplanar [dihedral angle 7.3 (1)°]. The acetamido group is twisted out of the plane of the aromatic ring in order to form an N-H⋯O hydrogen bond to the acetamido group of an adjacent mol-ecule, generating a helical chain running along the b axis.
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In the title compound, C(7)H(14)NO(5)P, the phosphate group displays rotational disorder of three O atoms with an occupancy ratio of 0.832 (6):0.167 (6). The dihedral angle between the acryl-amide group and PO(2) plane of the phosphate group is 75.69 (7)°. In the crystal, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the molecules.
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In the methanol solvate of the title 1:1 cocrystal, C(29)H(28)F(6)N(4)OS·C(5)H(9)NO(2)·CH(4)O, the l-proline mol-ecule exists as a zwitterion. In the crystal, the disubstituted thio-urea, l-proline and methanol mol-ecules are linked by N-H⋯O and N-H⋯N hydrogen bonds, forming a two-dimensional array in the ab plane.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812002899